Design and testing of high-density polyethylene nanocomposites
filled with lead oxide micro- and nano-particles: Mechanical,
thermal, and morphological properties
Abstract
This research discusses the mechanical behavior and the microstructure of high-density polyethylene (HDPE)-based composites,
manufactured using the melt-mixing and thermal-pressing techniques, where HDPE is mixed with various percentages of either bulk lead
monoxide (bulk PbO) or PbO nanoparticles (PbO-NPs) acting as fillers. The scanning electron microscope and the field emission transmission
electron microscope were utilized to identify the morphology of polymeric composites. Both showed the proper dispersion of PbO in the
HDPE matrix without substantial agglomerations. The effect of PbO on the thermal behavior of the HDPE was studied using the thermogravimetric
analysis. Tensile tests were implemented to find out how the mechanical characteristics of the composites were affected. Yield
stress, % elongation at break, stiffness, tensile energy (toughness), ultimate tensile strength, and ultimate tensile strain were elucidated in this
work. The values of stiffness, ultimate tensile strength, and yield stress increased by increasing either the bulk PbO or PbO-NPs’ loading up to
40.0 wt % with reference to the hosting matrix. The values of ultimate tensile strain, tensile energy, and % elongation at break of the assembled
composites diminished dramatically by increasing the filler’s content from 10.0 to 50.0 wt %. Besides, composites with PbO-NPs as a filler
were identified as having higher mechanical characteristics than those with bulk PbO for the same wt %.
Author(s)
Mohamed Mahmoud
Coauthor(s)
Ahmed El Khatib, Rehab El Sharkawi, Amal Rashed, Mohamed Salem Badawi, Mohamed Gepreel
Journal/Conference Information
Journal of applied polymer science,DOI: DOI: 10.1002/app.47812, Volume: 100, Issue: 1, Pages Range: 1-11,