Publications

The corrosion behavior of (SnO2)x(Bi1.6 Pb0.4)Sr2Ca2Cu3O10-d, (SnO2)x(Bi,Pb)-2223, in 0.5 M NaCl solutions at 30°C was studied using potentiodynamic polarization curves measurements, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) techniques as well as scanning electron microscopy (SEM) and energy dispersive X-ray emission spectroscopy (EDX). The polarization data indicated that SnO2 nanoparticles behave as a cathodic type inhibitor for the corrosion of (Bi–Pb)-2223 phase superconductors in simulating seawater solutions. The corrosion current density of (SnO2)x(Bi,Pb)-2223 in a NaCl solution decreases with the time elapsed from sample preparation. The CV of (SnO2)x(Bi–Pb)-2223 phase superconductors showed features similar to those of ideal capacitive behavior. The results indicated that a pure (Bi,Pb)-2223 phase superconductor is the most suitable choice for electrochemical capacitor applications in simulating seawater solutions. However, EIS measurements at different potentials revealed that the corrosion process is controlled not only by charge transfer but also by the diffusion process. These measurements also confirm that the corrosion rate of a cathodically polarized phase superconductor is less than that of an anodically polarized phase superconductor. SEM images and EDX analysis showed that the reduction of SnO2 nanoparticles to Sn decreases the corrosion rates of the superconducting materials.